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MSc Rasayan Vigyan study material:
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MSc I Sem
MCH-401: INORGANIC CHEMISTRY I
Unit-I Stereochemistry and Bonding in Main Group Compounds :
Unit-II Metal-Ligand Equilibrium in Solution
Unit-III Reaction Mechanism of Transition Metal Complexes
Unit-IV Metal-Ligand bonding
Unit-V HSAB Theory
MCH-402: ORGANIC CHEMISTRY I
Unit-I Nature of Bonding in Organic Molecules
Unit-II Stereochemistry
Unit-III Conformational analysis and linear free energy relationship
Unit-IV Reaction Mechanism : Structure and Reactivity
Unit-V Aliphatic Nucleophilic Substitution
MCH-403: PHYSICAL CHEMISTRY I
Unit-I Introduction to Exact Quantum Mechanical Results
Unit-II Approximate Methods
Molecular Orbital Theory
Unit-III Angular Momentum
Unit-IV Classical Thermodynamics
Unit-V Statistical Thermodynamics
MCH-404: Group Theory, Mathematics for Chemists and Biology for Chemists
Unit-I Symmetry and Group theory in Chemistry
Unit-II Vectors
Matrix Algebra
or Carbohydrates
Unit-III Differential Calculus
Or Amino-acids, Peptides and Proteins
Unit-IV Integral calculus
Or Lipid
Unit –V Permutation and Probability
Or Nucleic Acids
MSc II Sem
MCH-405: INORGANIC CHEMISTRY II
Unit-I Electronic Spectral Studies of Transition Metal Complexes :
Unit-II Magnetic Properties of Transition Metal Complexes
Unit-III Metal π-Complexes
Unit-IV Metal Clusters
Unit-V Optical Rotatory Dispersion and Circular Dichroism
MCH-406: ORGANIC CHEMISTRY II
Unit-I Aromatic Electrophilic Substitution
Aromatic Nucleophilci Substitution
Unit-II Free Radical Reactions
Unit III Addition Reactions
Unit-IV Addition to Carbon-Hetero Multiple bonds
Elimination Reactions
Unit-V Pericyelic Reactions
MCH-407: PHYSICAL CHEMISTRY II
Unit-I Chemical Dynamics
Unit-II Surface Chemistry Adsorption
Micelles
Unit-III Macromolecules
Unit-IV Non Equilibrium Theromodynamics
Unit-V Electrochemistry
MCH-408: Spectroscopy II and Diffraction Methods
Unit-I Nuclear Magnetic Resonance Spectroscopy
Unit II Nuclear Quadrupole Resonance Spectroscopy
Unit-III Electron Spin Resonance Spectroscopy
Unit-IV X-ray Diffraction
Unit-V Electron Diffraction
MSc III Sem
MCH-501: APPLICATION OF SPECTROSCOPY – I
Unit – I Electronic Spectroscopy:
Unit – II Vibrational Spectroscopy
Unit -III Nuclear Magnetic Resonance Spectroscopy – I
Unit-IV Nuclear Magnetic Resonance Spectroscopy – II
Unit-V Mössbauer Spectroscopy
MCH-502: PHOTOCHEMISTRY
Unit-I Photochemical Reactions
Unit -II Determination of Reaction Mechanism
Unit -III Photochemistry of Alkene
Photochemistry of Aromatic Compounds
Unit -IV Photochemistry of Carbonyl Compounds
Unit-V Miscellaneous Photochemical Reactions
MCH-503: Polymer Chemistry
Unit-I Basics
Unit-II Polymer Characterization
Unit-III Analysis and testing of polymers
Unit-IV Inorganic Polymers
Unit V Structure, Properties and Application of
MCH-504: Heterocyclic Chemistry
Unit-I Nomenclature of Heterocycles
Aromatic Heterocycles
Unit-II Non-aromatic Heterocycles
Unit-III Small Ring Heterocycles
Benzo-Fused Five-Membered Heterocycles
Unit-IV Meso-ionic Heterocycles
Six-Membered Heterocycles with one Heteroatom
Unit-V
Heterocyclic Systems Containing P, As, Sb and B
MSc IV Sem
MCH-505: APPLICATION OF SPECTROSCOPY
Unit-I Ultraviolet and Visible spectroscopy
Unit-II Infrared Spectroscopy
Unit-III Nuclear Magnetic Resonance of Paramagnetic Substances in Solution
Unit-IV Carbon-13 NMR Spectroscopy
Unit V Mass Spectrometry
MCH-506: SOLID STATE CHEMISTRY
Unit-I Solid State Reactions
Unit-II Crystal Defects and Non-Stoichiometry
Unit-III Electronic Properties and Band Theory
Unit-IV Organic Solids
Unit-V Liquid Crystals:
MCH-507: Chemistry of Natural Products
Unit-I Terpenoids and Carotenoids
Unit-II Alkaloids
Unit-III Steroids
Unit-IV Plant Pigments
Prophyrins
Unit V Prostaglandis
Pyrethroids and Rotenones
MCH-508: Organic Synthesis
Unit-I Disconnection Approach
Unit-II One Group C-C Disconnections
Two Group C-C Disconnections
Unit-III Oxidation
Reduction
Unit IV Organometallic Reagents
Unit V Synthesis of some complex molecules:
Chemistry Practical’s
After M.Sc. II Sem
Inorganic Chemistry
1. Separation and estimation of two metal ions:
(i) Estimation of copper and nickel both by gravimetric method
(ii) Estimation of barium gravetrically and copper volumetrically methods
(iii) Estimation of copper and zinc in a mixed solution of both by gravimetric methods.
(iv) Estimation of nickel and zinc in a mixed solution of both by gravimetric methods.
2. Preparation and synthesis of metal complexes
(i) VO(acac)2
(ii) Ni(acac)2
(iii) K3[Fe(C2O4)3]
(iv) Prussian Blue, Turnbull’s Blue.
(v) Co(NH3)6] [Co(NO2)6]
(vi) Hg[Co(SCN)4]
(vii) [Cu(NH3)4]SO4H2O
(viii) [Ni(NH3)6]Cl2
(ix) Ni(dmg)2
3. Paper chromatography:
(i) Ag(I), Pb(II) and Hg2(II)
(ii) Hg(II), Cu(II) and Pb(II)
(iii) Ni(II), Co(II) and Zn(II)
(iv) Ni(II), Co(II) and Cu(II)
Physical Chemistry
1. Chemical Kinetics
(i) Determination of velocity constant of the hydrolysis of methyl acetate catalysed by an acid (say HCl, H2SO4, etc.).
(ii) Determination of velocity constant of saponification of ethyl acetate with sodium hydroxide.
(iii) Determination of velocity of the reaction between potassium persulphate and potassium iodide.
2. Determination of composition of a mixture of weak and strong acids by conductor metric titration of following acids:
(i) HCl and CH3COOH
(ii) HNO3 and CH3COOH
(iii) H2SO4 and CH3COOH
3. Determination of composition of a mixture of weak and strong acids by pH metric titration of followings acids:
(i) HCl and CH3COOH
(ii) HNO3 and CH3COOH
(iii) H2SO4 and CH3COOH
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